Loading...
HomeMy WebLinkAboutMINUTES - 09171996 - D10 �. C) TO: 2 --a BOARD OF SUPERVISORS Contra FROM: Supervisor Jeff Smith "- ' , Costa Supervisor Mark DeSaulnier D ; September 17 1996 °� County DATE: ,;� SUBJECT: HAZARDOtJS MATERIALS ORDINANCE AND RELATED ISStJES SPECIFIC REOUEST(S)OR RECOMMENDATION(S)&BACKGROUND AND JUSTIFICATION RecommendationK 1. Discuss and determine the appropriate approach to assure safety in and around industrial facilities. A. Land use, Audit/Inspection, combination of both. B. Define which projects fit into which categories. C. Determine what to do about point score system. 2. Request Hazardous Materials staff,County Counsel,and County Administrator to report back to the full Board of Supervisors on September 24, 1996 concerning accusation about the process followed by the Hazardous Materials Commission in preparing the Land Use Ordinance and suggest proposal to avoid future problems. 3. Schedule a full report from the Ad Hoc Industrial Safety Committee and determination of actions for September 24, 1996,i.e.: Ask the Ad Hoc Safety Committee to have records for appropriate ordinance and appropriate policies ready for action by full Board of Supervisors by September 24, 1996. CONTINUED ON ATTACHMENT: X X YES SIGNATURE: __�2 RECOMMENDATION OF COUNTY ADMINISTRATOR RECOMMENDATION OF BOARD C M APPROVE OTHER VONATURE(S1: ACTION OF SOARD ON September 17, 1996 APPROVED AS RECOMMENDED X .,.. ��. OTHER ,..:4�_ The • Board CONTINUED to September 24 , 1996 , the staff report relative to the -Hazardous Materials Commission -and consideration of the "Hazardous Land Use Ordinance ; and APPROVED staff ' s Recommendation No . 3 . VOTE of SUPERVISORS _X UNANIMOUS(ASSENT - - - - 1 HERESY CERTIFY THAT THIS 18 A TRUE AYES: NOES: AND CORRECT COPY OF AN ACTION TAKEN ABSENT: AND ENTERED ON THE MINUTES OF THE BOARD ASSTAIN: OF SUPERVISORS ON THE DATE SHOWN. CC: ATTESTED September 17 , 1996 PHIL BATCHELOR,CLERK OF THE BOARD OF SUPERVISORS AN COUNTY ADMINISTRATOR M382 (10/88) BY DEPUTY 1I Background On June 25, 1996 the Board of Supervisors adopted Ordinance 96-20, a Hazardous Materials Land Use Ordinance which was developed by the Hazardous Materials Commission. Recently some members of the environmental community have challenged the process by which this ordinance was developed. Specifically they have implied that the point score system used in the ordinance was skewed in order to assure that certain industrial projects did not require land use permits. The Ad Hoc Industrial Safety Committee has been meeting to consider a number of ordinances to address safety issues around refineries. They had a sub-committee meeting this Thursday to further discuss these issues. The committee would like some policy direction from the full Board of Supervisors concerning some of these issues. Land-U-se_Contr_oLvs.-Audits and nspections The Hazardous Materials Commission suggested a land use approval to assure safety in heavy industrial projects. The Industrial Committee has suggested an ordinance which relies upon audits and inspections of facilities. If the land use approach is continued we need to define: 1. Which projects will require Land Use Permits. 2. Whether or not to use the point score system. 3. What building inspection requirements there will be. If the audit inspection approach is taken,we need to be certain that the county will retain this authority, both before and after the implementation of Risk Management Plans(RMP's)pursuant to SB 1889(Calderon) and the Federal Clean Air Act. The Committee needs your policy direction regarding these issues. Hazardous-Materials Commission_P__rocess There has been a challenge to the process taken by the Hazardous Materials Commission. We think there should be a report from staff regarding the issues and recommendations to avoid problems in the future. t COMMUNITIES FOR A - ' �ETTER September 9, 1996 R E C E I V E C� RONMENT or ly`Citizens'for a Better Environment-California SEP 1 01q%, ' Fair Political Practices Commission Attn: Intake Review ctsRrc ao,,l'c suPEuv s��S CONTRA Cc)STA CO- P.O. Box 807 - Sacramento, CA 95812, Jeff Smith Ramiro Arosemena Chair. -.Foreman Contra Costa County Board of Supervisors Contra Costa County Grand Jury 651 Pine Street 1020 Ward Street Martinez, CA 94553 Martinez, CA 94553 Re: . Potential Conflict of Interest: Contra Costa County Hazardous Materials Commission Member Tom Lindemuth Ladies and Gentlemen: We are writing to express our. concern about potential conflicts of interest ..for Tom.Lindemuth, a member of the Contra Costa.County Hazardous Materials Commission. Mr. Lindemuth has been participating in County�decisionmaking regarding the provisions of an ordinance that subjects certain industrial facilities to land use review. At the same time, he has been representing an industrial client for the purpose of persuading the County that this.client's project is exempt from land use review under the Ordinance. We believe this dual representation may violate j, the California Political Reform Act and County ordinances and policies regarding. conflicts of interest and financial disclosure. We.are requesting your help in investigating Mr. Lindemuth's activities and, if necessary, taking appropriate enforcement action.' - Facts The Commission was established pursuant to Health and-Safety Code section. J 25135.2. Its function is to assist the County in preparing and administering the County's.hazardous waste management plan. (Ibid.) Section 251.35.2 requires that such advisory committees consist.of.at least one representative of industry, one 1 representative of an environmental organization and one representative of the .r public. The statute also requires the Board of Supervisors to appoint, to.the extent 1 This letter constitutes a formal complaint to the Fair Political Practices Commission(TPPC")under Government Code§83115 and 2 CCR§18360. 500 Howard Street, Suite 506 San Francisco, CA 94105 (415) 243-8373 In Southern California:605 W. Olympic$IFd.;Suite 850 • Los Angeles;CA 90015 • (213)486-5114 possible, other members that have expertise including, but not limited to, engineering, geology and water quality. The Contra Costa County Board of Supervisors appointed the Hazardous Materials Commission in 1986. In addition to the city representatives required by the statute, the Board of Supervisors appointed the following representatives: two industrial, two environmental, one taxpayers, one League of Women Voters, one labor, one public and one environmental engineering. Mr. Lindemuth was Aa appointed to the Commission to represent environmental engineering firms. "a The Board of Supervisors charged the Commission with a broader set of responsibilities than are set forth in section 25135.2, including drafting a hazardous materials ordinance for consideration by the Board of Supervisors. The Ordinance was drafted by the Commission's Planning and Policy Development Committee, which was chaired by Mr. Lindemuth. The Ordinance drafted by the Committee requires permits for projects involving hazardous wastes or materials at industrial facilities (e.g., oil refineries, chemical plants) that exceed a specified hazard score (point total). The hazard score is based on a consideration of a number of risk -.d factors (e.g., amount of hazardous materials involved, proximity to residences, etc.) On June 18, 1996, Mr. Lindemuth presented the Ordinance drafted by his Planning and Policy Development Committee to the Board of Supervisors for its consideration. The Ordinance was adopted by the Board. We believe that the first project considered by the County under the new Ordinance is a project at the Unocal oil refinery in Rodeo. Unocal hired Mr. Lindemuth, along with other consultants, to evaluate the hazard score of the Unocal project under the Ordinance and to present a report to the County describing their conclusions. The report prepared by Mr. Lindemuth and Unocal's other consultants concluded that the hazard score for the project was not high enough to trigger County land use review. Although we do not know the details of when Mr. Lindemuth provided these services to Unocal or was paid for his work on the Unocal project, the report prepared by Mr. Lindemuth and the other consultants is dated August 5, 1996, and was presented to the County on August 7, 1996. (Exhibit A) It appears that, on several occasions, Mr. Lindemuth has participated in ry County decisionmaking in his capacity as a member of the Hazardous Materials Commission where those decisions could have a material financial effect on the Unocal application that he helped prepare as a paid consultant. Since adoption of the Ordinance in late June, the Board of Supervisors, the Planning Commission and the Hazardous Materials Commission have been considering amendments to the Ordinance proposed by a coalition of environmental, community and labor groups, and by the County Community Development Department staff. These amendments include proposals to lower ._� the hazard score that triggers the County permit requirement under the Y+ ri Ordinance. On June 25, 1995, Mr. Lindemuth presented testimony in his capacity as Chair of the Hazardous Materials Commission's Planning and Policy Development Committee to the Board of Supervisors, in which he opposed any amendments to the new Ordinance, including amendments to lower the hazard score. On July 15, 1996, Mr. Lindemuth again testified regarding the proposed amendments to the Ordinance at a meeting of the Board of Supervisors' Ad Hoc Committee on �J Industrial Safety. On July 29, 1996, Mr. Lindemuth pard -ipated as a member of the Hazardous Materials Commission at a joint meeting of the Commission, the Ad Hoc Committee on Industrial Safety and the County Planning Commission. At this meeting, Mr. Lindemuth presented oral and written comments opposing the proposed amendments to the Ordinance, and specifically opposing any lowering of the hazard score that would trigger County permitting. On August 29, 1996, Mr. Lindemuth testified at another meeting of the Ad Hoc Committee on Industrial Safety. He indicated that he was testifying as a Chair of the Commission's Planning and Policy Development Committee. On this occasion, Mr. Lindemuth indicated that he was opposed to the County staff recommendation that the hazard score for County permitting be lowered to 60 points. He did not publicly disclose on this or any other occasion that he had prepared a report for Unocal on a project currently pending before the County that rated a hazard score of 61. Legal Standards A. State Laws and Regulations 71 The Political Reform Act provides as follows: No public official at any level of state or local government shall make, participate in making or in any way attempt to use his official position to influence a governmental decision in which he knows or has reason to know he has a financial —' interest. (Gov't Code § 87100.) Public officials are defined as "every member, officer, employee or " consultant of a state or local government agency . . . ." (§ 82048.) A 'local government agency" includes any commission of a county. (§ 82041.) ti The FPPC's regulations define "participates in making a governmental decision" as advising or making recommendations to the decisionmaker by, inter aha, preparing reports, analyses, or opinions requiring the exercise of judgment and for the purpose of influencing a governmental decision. (2 CCR § 18700(c)(2)(B).) An official is financially interested in a decision "if it is reasonably :.i .fit --i � f foreseeable that the decision will have a material financial effect, distinguishable from its effect on the public generally, on the official" or on, inter alia, a source of income of at least $250 over the year prior to the decision. (§ 87103.) B. County Standards The Contra Costa County Board of Supervisors ("Board") has issued a policy statement regarding conflicts of interests for members of the Commission. (See Exhibit L'; pp. 4-5 (Section VI of the Cc,nmission's bylaws).) This policy summarizes the Board's general confli,-t of interest policy for Board appointees, and notes that all officials should "avoid even any appearance of conflict of interest." (Id., § VI.A. (citing Board Resolution No. 82/574).) The Board's intent is for these general policies to apply to the Commission members. However, this policy expressly states that the Commission members are intended to represent and further the interest of specified industries and groups responsible for their nomination. For members � nominated by a trade, industrial, or professional group, these groups are deemed to constitute a significant segment of the public under Government Code section 87103. (Id., § VI.B.) Potential Violations Mr. Lindemuth is advising and making recommendations to the Board about the Ordinance at the same time Unocal has an application pending with the County t= that could be materially affected by the Board's decision about the Ordinance. Hence, he may be participating in a decision in which he knows he has a financial interest.2 If so, Mr. Lindemuth should have disqualified himself from participating in the Ordinance amendment process. At the very least, he should have disclosed his financial interest to the public and the Board.3 It is entirely proper for Commission members to represent various segments ,x that will be generally affected by the Ordinance. (See Health & Safety Code § 25135.2) Thus, there is no conflict of interest for Mr. Lindemuth to participate in governmental decisions which may affect environmental engineering firms. However, Mr. Lindemuth has participated in a governmental decision which could materially impact his industrial client on a specific application currently 2 If Unocal paid Mr. Lindemuth more than$250 during the past year, Unocal is a "source of income" per Government Code section 87103. Although the Board has issued a policy statement that the Commission members represent a"significant segment of the public"for purposes of section 87103, Mr. Lindemuth was appointed to represent engineers, not industry. 3 Even if Mr. Lindemuth is not prohibited from participating in the ordinance amendment process, he may be required to disclose his financial interest in the decision. See, e.g., Consumers'Union of United States, Inc. v. California Milk Producers Advisory Bd. (1978) 82 Cal.App.3d 433, 448, 147 Cal.Rptr. 265, 274; Metropolitan Water District v. FPPC (1977) 73 Cal.App.3d 650, 658, 141 r� A pending before the County. His participation may have a direct and immediate impact and, thus,.may constitute a prohibited conflict of interest. There was no public disclosure of Mr; Lindemuth's connection with Unocal, and Mr. Lindemuth did not recuse himself from participating in the decisionmaking process'for the Ordinance. Hence, there was no way for the public to know whether Mr. Lindemuth was acting on behalf of the general public, the engineering.profession,.or Unocal when he participated in this decisionmaking process. The public has a right to know that public decisionmaking is not tainted by -, an official's personal economic interest. There should be no shadowy revolving door where Mr. Lindemuth sometimes appears as a public official and other times appears as a private consultant for an industrial client. His actions raise serious and. ' fundamental questions about the integrity,of the County's processes. The County's _ citizens must now ask themselves for whose benefit was the new hazardous materials ordinance written? is it to protect the public from continued industrial accidents, or was it to shield the industry from public scrutiny? - For-those of us whose families are threatened by industrial fires and explosions and whose houses lie in the path of toxic releases, these are crucial questions. We - believe we are entitled to•a government of disinterested integrity. We ask your help in resolving this matter and-in restoring confidence in our public processes. Very trulyy ours, �g Andy chlin Shoreline Env ronmental Alliance Denny Larson Sall�Soon4e Communities for a.Better Environment Good eighbor. Coaltion . onald Brow Good'Neighbor Coalition Enclosures cc: Vic Westman, Contra Costa County Counsel Jim Rogers, Supervisor Jeff Smith, Supervisor Gayle Bishop, Supervisor Mark DeSaulnier, Supervisor Tom Torlakson, Supervisor 5 VERIFICATION I, QPM,► L�riS� declare: I am the C of —C�'' b' =— -------- I. 'have read .-, the foregoing letter regarding potential conflicts of interest and know. the contents 'thereof. The same is true of my own knowledge, except as to those. y n matters which are therein alleged on information and belief, and as to those matters, .I believe them to be true. I declare under penalty..of perjury under the laws of the State of California that the foregoing is true and correct. Executed at at California. cJ " LA Fti 'I' 1rC.OS :A , , 'iPRODUCTSCOMPANY 1-�-i ' A EAD-380-96 P,1J1^1 -7 PH 4: 23 HW-7.7.1.2 "VELOPME' T DEPT r a n c i s c o Refinery CERTIFIED MAIL RETURN RECEIPT REQUESTED Z 764 379 102 August 5, 1996 Harvey E. Bragdon Director Community Development Department Contra Costa County 651 Pine St., 4th Floor, North Wing Martinez, California 94853 Dear Mr. Bragdon: ORDINANCE NO. 96-20; UNOCAL SELENIUM REMOVAL PROJECT Unocal is undertaking a project to install facilities to remove selenium from its waste water discharge. Because the project involves the handling of hazardous waste, Unocal has reviewed the above Ordinance for applicability to the project. Unocal has determined that the project requires neither an application for a permit nor an application for determination of exemption or noncoverage because the project score is under 69, and when compared with Unocal's three year hazardous waste baseline, does not increase the amount of hazardous waste handled at the Refinery (84-63.802). However, because the Ordinance 96-20 is brand new and no one has any experience with its scoring methodology, we have attached to this letter materials, including our scoring of the project upon which we based our determination. Unocal requests that your department review these materials for the purpose of confirming our determination of nonapplication. While this letter and the enclosures are not an application under the ordinance, we have enclosed a filing fee in the amount of$140.00 because we realize that the County staff will have to review Unocal's scoring of the project in order to accommodate our request for confirmation of our determination of nonapplication. 1380 San Panio Avenue Rod:: --ah!arnla 3,1572 1293 µ Harvey E. Bragdon EAD-380-96 August 5, 1996 HW-7.7.1.2 Page 2 rj In addition, we have enclosed for your information an analysis indicating that the project is exempt from the ordinance because it is a project that is being undertaken solely to comply with an order of the Regional Water Quality Control Board for the San Francisco Bey Region(Section _ 84-63.604 (a)). As we understand the new ordinance, if you concur with our determination of nonapplicability under Section 84-63.802, no determination under the exemption provisions of Section 84-63.604 (a) will be required. We will be happy to meet with you and your staff to discuss this matter and the enclosures at your convenience. Sincerely, a� Hilding K. Spradlin Senior Advisor, Environmental Programs -71 HKS/dm vl� Enclosure Unocal - 76 Products Company San Francisco Refinery Selenium Reduction Project County Land Use Evaluation August 5, 1996 riN Evaluation Conducted By: Hilding K. L. Spradlin, R.E.A Thomas E. Lindemuth, P.E. Quang Q. Bui, R.Ph., Ph.D., D.A.B.T. J. Phyllis Fox, Ph.D. 1380 San Pablo Avenue Rodeo, California 94572-1299 Table of Contents 1.0 Introduction 1 { 2.0 Background 1 3.0 Project Description 1 4.0 Baseline Determination 3 • Facility Storage Baseline 3 • Transportation Baseline 10 _1 5.0 Project Determination 16 • Selenium Reduction Project Storage Amounts 16 • Selenium Reduction Project Transportation Amounts 18 6.0 Assessment of Risk Elements 20 -- 7.0 Non-Coverage 24 -3 8.0 Exemption 24 9.0 Conclusions 24 Appendix A Appendix B .,y ;1 1.0 Introduction This evaluation has been conducted to determine whether Unocal's planned selenium reduction project to be constructed at its San Francisco Refinery (SFR) will require: (1) d an application for an exemption; (2) an application for non-coverage; and (3) a land use permit under Contra Costa County's newly adopted land use ordinance (Ordinance No. 96-20, adopted June 25, 1996). - 2.0 Background In February 1991, the San Francisco Regional Water Quality Control Board (RWQCB) issued an order to six Bay Area refineries limiting selenium discharge to 50 parts per billion (ppb). For SFR, this 50 ppb standard equals a mass emission rate of 0.85 pounds per day. The order requires SFR to meet the 50 ppb daily maximum limit and the 0.85 pound per day annual rolling average mass emission rate on or before July 31, 1998. 3.0 Project Description Unocal plans to use ion exchange technology to meet the 50 ppb selenium discharge limit. The following describes the process. The sour water stripper effluents are combined in a feed/surge tank. The combined water flows through a clarifier and a garnet/anthracite filter to reduce the water's oil and solid content. This water then flows through two ion exchange resin beds arranged in series. When the first bed becomes loaded with selenium, a spare column will be put into service and the loaded column will be taken off-line for regeneration. A fourth column is on stand-by as a spare. A salt solution regenerates the loaded bed by removing the selenium from the resin. The selenium in the selenium-rich regenerant is then precipitated in a series of stages and ultimately de-watered and sent off-site for metals recovery and/or disposal. The selenium-lean regenerant is then reused to regenerate the next bed of selenium-loaded resin. Refer to Figure 1 for a simplified process flow diagram. Y, 7 4.0 Baseline Determination _a 1995 calendar data has been used to prepare the facility's baseline. This is the most recent time period for which twelve months of data are available. Facility torage Baseline The facility storage baseline has been developed primarily from SFR's AB 2185 Business Plan. In so doing, we are using information consistent with previous reports to the county. Table 1 summarizes the list of hazardous materials and wastes stored at SFR in 1995. w Amounts given for each material are in pounds and represent the maximum amount of material or waste stored at any one time during the year. Additionally, each material and waste has been assigned and summarized in this table to a DOT hazard category pursuant to Contra Costa County Land Use #96-20, Article 84-63.1016. The amounts, given as the ma dmum tons stored at any time, (ordinance section 84- 63.430) are approximately 81"i tons of category A materials and wastes, 543000 tons for category B materials and wastes, and 584000 tons for category C materials and wastes. In developing these baseline totals, we have excluded quantities of material stored in containers less than 42 gallons. yi -3 - Table 1 -' List of Hazardous Materials and Wastes Stored in Refinery in 1995 -- Baseline Common Name Chemical Name/Composition Haz. Category A Haz. Category B Haz. Category C (pounds) (pounds) (pounds) Acetone Acetone 1447 Acetylene Acetylene 167 _ Activated Alumina Activated Alumina 1594 Activated Carbon Carbon 159916 ADA Elvada-Anthraquinone Disulphonic Acid 27479 Adsorbent,H-I Sodium/Calcium/Aluminosilicate 117460 Adsorbent,H-15 Sodium Calcium Aluminosilicate 58800 Adsorbent,H-2 Activated Carbon 236.30 - Adsorber Charge Mix Iso-&N-C5,C6 37478 Adsorber Effluent Mix iso-05,C6 2154 -� Ammonia(Anhydrous) Ammonia(Anhydrous) 53166 Ammonia Acid Gas Ammonia Acid Gas 186 Ammonia Hydroxide Ammonia Hydroxide 131215 Ammonia Sulfide Water Ammonia Sulfide Water 9251 - Ammonium Polysulfide Mixture 8693 Anderoi 497 Anderol 497 158 Anthracite(Coal) Coal 13956 AO-37 AO-36,UC-200 38518 Argon Argon 946 Aristowax Aristowax 6647394 ATF Multipurpose ATF Multipurpose 824 Ballast Water Oil,Petroleum n.o.s. 5053656 Betz 2023 M<<ture 10445 F Betz 20K Mixure 7461 Betz 20K-20275 Mixture 4663 Betz 20K-20435 Mixture 2093 Betz 407C Mixture 2830 Betz AD-9 Mixture 431 Betz Balanced Polymer 5430 Mixture 2748 Betz Balanced Polymer 64Y21 Mixture 19985 Betz Balanced Polymer 7417 Mixture 9118 Betz Balanced Polymer AP-11I Mixture 1832 Betz Balanced Polymer CF-I Mixture 916 "- Betz Corr-Shield Mixture 3056 Betz Corr-Shield 736 Mixture 118 -_ Betz Corr-Shield K-7 Mixture 2198 Betz Corr-Shield/water Mixture 1665 Betz Corrogen Mixture 13790 Betz CS-736 Mixture-Bea proprietary 543 Betz CTP 23 Mixture 4867 Betz Inhibitor 20K Mixture 1166 Betz Inhibitor 29K-35144 Mixture 1800 Betz Optimeen 80102 Mixture 12449 Betz Optimeen 80103 Mixture 905 Betz Petrouneen AF 107 mixture 824 Betz Petromeen AF-111 Mixture 8785 Betz Petromeen FC-644 Mixture 7078 Betz Petromeen OS-16 Mixture 17112 Betz Slitnicide C-31 Mixture 13057 Betz Slimicide C-77P Mixture 1016 Betz Slimicide 1-12 Mixture 167 BHT 2,6di-cert-butyl-4-methylphenol 202 BRAYCO 1350 Brayco 1350 426 Brine Water and Salt 229176 Bubble Tower Bottom Heavy Thermalcracked Distillate 214197 Bunker Fuel Oil Fuel Oil,No. 8 31953 Banker No. 6 Residual Fuel Oil Fuel Oil,No.6 2348 Butane N-Butane 7421709 Butane&Lighter Butane&Lighter 55328 C5,C6 Hydrodesutlfurized Light Naphtha 17228762 C7 Light Naphtha,C4 to C6 11819610 Carbon Dioxide Carbon Dioxide 976 Carbon Dioxide/water Mix Carbon Dioxide and H2O 853 Cat Gas Oil Cat Gas Oil 47021438 4 — Note: Sources for this table are the Refinery's 1995 Business Plan. 1995 Biennial Report to Cal-EPA,and excluded recyclable material records of transport. ,t Table 1 List of Hazardous Materials and Wastes Stored in Refinery in 1995 -- Baseline Common Name Chemical Name/Composition Haz.Category A Haz. Category B Haz.Category C (pounds) (pounds) (pounds) Catacarb 274 Catacarb 274 27021 Catacarb Inhibitor 100-H Catacarb Inhibitor 100-H 6485 Catacarb Solution SFR Catacarb Solution 700380 Catacarb WBU Catacarb WBU 11651 Catalyst, E-603 Catalyst Mixture 27978 Catalyst, 11-3 Catalyst Mixture 28529 Catalyst,23-1,3,&4 Catalyst Mixture 116856 „{ Catalyst,32-4 Catalyst Mixture 44606 Catalyst,83-2 Catalyst Mixture 101034 Catalyst,AS-100 Catalyst Mixture 64034 _n Catalyst,C11-9-02 Catalyst,C11-9-02 504 Catalyst,C11-9-09 EW Catalyst,C11-9-09 EW 22320 "t Catalyst,CII-NK Catalyst,CII-NK 12893 Catalyst,C12-4-02 Catalyst,C124-02 35932 Catalyst,C20-6-03 Catalyst,C20-6-03 5320 Catalyst,Claus A-203(C1) Activated Alumina 35829 -- Catalyst,E-611 Catalyst Mixture 113449 Catalyst,E-803 Catalyst Mixture 122462 Catalyst,E-804 Catalyst Mixture 55376 Catalyst,G72D Catalyst,G72D 12254 _d Catalyst,G72D Catalyst,G72D 12260 Catalyst,HC-26/28,HCK Catalyst Mixture 439269 Catalyst,HCD,HCK Catalyst Mixture 56441 Catalyst,HCK Catalyst Mixture 61505 Catalyst,HCK/AF-542 Catalyst Mixture 728793 Catalyst,HS-10,denstone Catalyst Mixture 133210 Catalyst,Katalco 41-6 Catalyst Mixture 33886 Catalyst,Katalco 71-1 Catalyst Mixture 138907 Catalyst,KF-844 Catalyst Mixture 10988 Catalyst,N-25,N-39 Catalyst Mixture 33711 Catalyst,S-501 Catalyst Mixture 193747 Catalyst,TSR-11 Catalyst Mixture 98309 ' Caustic(spent) Caustic(spent-mixture varies) 3768933 Caustic Soda 25 Baun Soduim Hydroxide 57256 Chesterton 380 Machinery Coolant Chesterton 380 Machinery Coolant 486 1 Chlorine Chlorine 24980 Citra Super Parts Degreaser D-Limonene 458 "'d Coker Cracked Naphtha,SMPD Heavy Thermocracked Naphtha 16093 Condensate 50% steam/507. water 9734 Cracked Naphtha Cracked Naphtha 110502285 Cracked Naphtha/water Oil,Petroleum n.o.s. 12515 Crude Oil Petroleum Crude Oil 18672 344390422 Cycle Oil Heavy Hydrocracked Distillate 290911 D-106 Bottom Hydrodesulfurized Heavy Naphtha 16714 D-201Dehexanizer Bottom Heavy Thermocracked Naphtha 39167 -- D-201Dehexanizer Overhead Lt.Naphtha C4-C6 115796 Debutanizer Feed Light Hydrocracked Distillate 59077 y Dewaxed Long Raffinate Solvent Dewaxed Light Paraffinic Distillate 4008 8570681 Diala AX Oil Diala Oil AX 8537 3 Diatomaceous Earth Diatomaceous Earth - 632 Diesel No.2 Fuel Oil,No.2 142346332 Diesel Ref Fuel Fuel Oil,No.2 1539 Dye,Automate Red B Dye,Automate Red B 13540 Epolene-C-18 Mixture 120000 Ethane and Lighter Ethane and Lighter 737 Ethanol Ethanol 376 Excluded Recyclable Material Wastes used off-site as Raw Material Feed 227143 Extract Extract 22875 Foots Oil#143 Foots Wax 701434 Foots Oi 1MMK Foots Wax and M1BK 13115 Foots Oils-143/165 Foots Oils 1596536 A Freon 11 Trichlorofluoromethane 1568 Fuel Gas Mixture 984 Fuel Gas(sour) Refinery Sour Fuel Gas 5713 — 5 — Note: Sources for this table are the Refinery's 1995 Business Plan, 1995 Biennial Report to Cal-EPA,and excluded recyclable material records of transport. Table 1 List of Hazardous Materials and Wastes Stored in Refinery in 1995 -- .Baseline Common Name Chemical Name/Composition Haz. Category A Haz. Category B Haz. Category C (pounds) (pounds) (pounds) Fuel Oil/t6 Fuel Oil,No.6 23094102 Fyrquel 550 R and 0 Fyrquel 550 R and 0 1832 Gas- Liquid Mixture 50%H2,H2O,CO2,C114:50%liq.H2O 12124 Gas Mixture:CO/N2 Mixture 278 -� Gas Mixture:CO2/Argon 75%Argon 25% CO2 278 Gas Mixture:CO2/N2 Mixture 31 Gas Mixture:H2/Ethane/Methane Mixture 9 Gas Mixture:H2S/N2 Mixture 33 Gas Mixture:Helium/Methane Mixture 18 Gas Mixture:Methane/Ethane Mixture 17 `?l Gas Mixture:N2/Methane Mixture 9 Gas Mixture:NOx/N2 Mixture 93 Gas Mixture:02/N2 Mixture 301 Gas Mixtum:Pentane/Butane 3% iso-Butane 3%a-Pentane 94%n-Butane 9 -' Gas Mixture: Propane/Butane 3%n-Butane 3% Propane 94% iso-Butane 9 i Gas Mixture:S02/Air Mixture 22 Gas Oil Light Paraffm Vacuum Distillate 35275 Gasoline Gasoline 205610313 Gasoline Range-Sour C7-C9 Sour C7-C9 13690 Glycol Diethylene Glycol 280 GW Solv 1 Mixture 1356 GW Solv 225 Mixture 1356 GW Solv 325 Standard Solvent 1447 3 GW Solv 450 Standard Solvent 360 Hazardous Waste Hazardous Waste 220355 195772 335896 HCGO Heavy Thermalcracked Distillate 23037569 Heavy Reformate Heavy Reformate Naphtha 47165 Helium Helium 52 Heptane N-Heptane 1896 Heptane and heavier Mix Hydrodesulf Nap,Lt Naphtha C4-C10 27813 Hexane and Lighter Hydrodesulfurized Light Naphtha 14049 Hot Oil(D-305) Hvy Hydrocracked Distillate 25493 ..a HUK Light Hydrocracked Distillate 22393237 HUN-Heavy Unionfined Naphtha Hydrodesulfurized Heavy Naphtha 16467 HUSD Hydrodesulfurized Kerosene 165001 t Hydrogen Hydrogen 2623 Iso-Butane Iso-Butane 48157 Isomerate Light Naphtha,C4 to C6 18960239 Isopentane Isopentane 19285 Isopropyl Alcohol Isopropyl Alcohol 1085 ISOSIV Molecular Sieve Adsorbent Catalyst Mixture 328767 Jet A Fuel,Aviation.Turbine Engine 109176743 Jet A-Turbine Fuel Fuel,Aviation,Turbine Engine 25786 Lapping Vehicle q 3 #REF! 383 LCGO Light Thermalcracked Distillate 23072468 -- Lean MEA Monoethanolamine 452431 Lean Oil Light Hydrocracked Distillate 143923 Lectra Clean II Lectra Clean II 829 Light Diesel Light Gas Oil 25558 14860806 Light Naphtha From U267 Full Range Straight Run Naphtha 3512 Light Oil Light Oil 24182 Light Waxy Gasoline Light Naphtha C4 to C10 34595 Long Waxy Raffinate Solvent Deasphalted Residuum 433597 Long Waxy Resid Vacuum Tower Bottoms 25834080 Low Sulfur Fuel Oil Fuel Oil,No.4 16391603 Lube Oil Oil,Petroleum n.o.s. 52817975 LUK Light Hydrocracked Naphtha 17139984 4 LUSD Hydrodesulfurized Kerosene 3560 Magnaformate Full Range Reformate Naphtha 40470 Make Gas Mixture 1713 MEA Monoethanolamine 187429 MEA Acid Gas(H2S) MEA Acid Gas 376 Medium Waxy Naphtha Heavy Naphtha 48179 Methel Ethol Ketone 2-Butanone 1099 6 — Note: Sources for this table are the Refinery's 1995 Business Plan, 1995 Biennial Report to Cal-EPA,and excluded recyclable material records of transport. —s, 77, -.3 Table 1 List of Hazardous Materials and Wastes Stored in Refinery in 1995 -- Baseline 7 Common Name Chemical Name/Composition Haz. Category A Haz.Category B Haz. Category C (pounds) (pounds) (pounds) F MIBK Methyl Iso-butyl ketone 161710 Mid-Barrel USD Hydrodesulfurized Kerosene 22966265 Mineral Oil,Heavy Mineral Oil 412 Mineral,Light (Blandol) Mineral Oil 1237 Mix Butane Mix Iso-Butane,N-Butane 249761 Mix Crude Oil/water Petroleum Crude Oil and H2O 201177 Mix Dewaxed Long Raffmate/Propa Mix Sol.Dewaxed Lt.Paraffinic Dist&Propane 132004 jMix Extract, Phenol Mix Extract,Phenol 179491 Mix Extract, Phenol,Propane Mix Extract,Phenol,Propane 729568 ,fix Extract,Raffinate,Propane,Ph Mix .:tract,Raffinate,Propane,Phenol 6203 'z3 -Mix Gas Mixture 1045 Mix MMK,Water Mix MIBK,Water 4527 " -Mix Phenol,Propane,water Mix Phenol,Propane,H2O 7271 Mix Phenol,water Mix Ph�.:ol,H2O 26644 Mix Raffinate, Phenol Mix Raffinate,Phenol 32019 Mix Raffmate,Propane,Phenol Mix Raffinate,Propane,Phenol 25916 -a Mix Solvent Slack Wax,Clay Mix Solvent Slack Wax,Clay 52722 Mix Solvent Slack Wax,MIBK Mix Solvent Slack Wax,MIBK 134518 Mixed Resid Mixed Resid 29985691 Mobiltherm 603 /#REF! 1749 Motor Oil (Guardol 30) Oil,Petroleum n.o.s. 2061 Motor Oil lOw/40 Unocal Super Motor Oil lOw/40 948 .,� MP Gearlube 80w/90 Unocal MP Gearlube 80w/90 115 MTBE Methyl cert-butyl Ether 70506374 w MUK Heavy Hydrocracked Naphtha 29648168 N-Butane N Butane 251 Nalco 1193 Mixture 275 Nalco 39M Mixture 1035 Nalco 5165 Mixture 8714 Nalco 5196 Mixture 18239 Nalco 5196&Petrohte 1150 Nalco 5196&.Petrolite 1150 5386 Nalco 5537 Mixture 8618 Nalco 5651 Mixture 265215 Nalco 5707 Mixture 5111 Nalco 7156 Mixture 120858 Nalco 7330 Mixture 2748 Nalco 7346 Mixture 475 Nalco 8305 Mixture 5995 Naphtha(sour) Hydrodesulfurized Heavy Naphtha 12676 Naphtha.stabilized Heavy Thermalcracked Naphtha 32295 Natural Gas Natural Gas 35 Nitrogen Nitrogen 541011 Nitrous Oxide Nitrous Oxide 128 Octane(88-Octane Reference Fuel) Mixture 2565 Oxygen Oxygen 492 Petrolite 1150 Mixture 2729 Petrolite 1330 Mixture 2844 Phenol Phenol 658079 Phenolic Water Mixture 444840 Phosphoric Acid Phosphoric Acid 28312 Potassium Hydroxide 50% Solution Potassium Hydroxide 1701235 Prime Cleaner Mixture 916 Process Water Refinery Process Waste Water 137845 6735427 Propane Propane 2410389616 Propane and Lighter Propane and Lighter 15983 Propane Vapor Propane Vapor 22181 Propane/Long Waxy Raffinate Propane and Solvent Deasphalted Residuum 16238 PSA H-2 Adsorbent Activated Carbon 38121 �. PSA H-3 Adsorbent Silica Gel 21453 PSA H-5 Adsorbent Activated Alumina 1738 PSA Offgas PSA Offgas 650 Raffinate Raffinate 11324 "+ Reactor Charge Mix H2&Lt Hydrerckd Distillate 192747 Reactor Effluent Mix H2.Hvv Hydro Naphtha 114516 f — 7 — Note: Sources for this table are the Refinery's 1995 Business Plan. 1995 Biennial Report to Cal-EPA,and excluded recyclable mate^al records of transport. • 0 Table 1 List of Hazardous Materials and Wastes Stored in Refinery in 1995 -- Baseline ��,1 Common Name Chemical Name/Composition Haz. Category A Haz. Category B Haz. Category C (pounds) (pounds) (pounds) Reactor Effluent(sour) Mixture N2,H2S,SO2,H2O 761 Reactor Feed Mix H2, Lt Hydrerckd Distillate 195 Recycle Gas Hycrocracked Gas H2 Rich Cycle 995 Reformate Splitter Overhead Light Reformate Naphtha 22942 ' Reformate,Magnaformate Light Reformate Naphtha 39950301 Reformer Charge Mix H2&Hvy Hydreracked Naphtha 67200 Reformer Effluent Mix H2&Hvy Hydreracked Naphtha 73416 ! Regular W TK 287 Gasoline 2033 Rich MEA Monoethanolamine&H2S 26422 Rich Oil Light Hydrocracked Distillate 10604 est Rich Stretford Solution Mixture Sulfer&Stretford Solution 3380599 SCTGO Intermediate Gas Oil 90928 SCTGONTLGO Light Thermal Cracked Distillate 2525 Seal Oil Oil,Petroleum n.o.s. 8774 Seal Oil/water Oil,Petroleum n.o.s. 17695 .f_ Secondary Crude Tower Feed Petruoleum Crude Oil 179971 Silica Gel K3 Silica Gel 367 Silicone SWS-03461 Silicon SWS-03461 69320 Silicone Union Oil 50/50 Blend Silicon Union Oil 50/50 Blend 2446 Slack Wax Solvent Slack Wax 10669891 Slops,Recoverable Oil Waste Petroleum Oil,n.o.s. 12977215 SMGO Intermediate Gas Oil 75066496 Soda As?: Sodium Carbonate,Anhydrous 141572 Soda Ash(Water Mixture 8327 k. Sodium .y nwonium Vanadate Vanadium Compounds(Elvan K) 7914 Sodium Hydroxide Sodium Hydroxide 11010 Sodium Hydroxide 15-20%Baun A Mixture 11866 Sodium Hydroxide 50%Solution Sodium Hydroxide 788107 Sour Water Refinery Water 3672207 Sour Water Sour Water 50320 206963 Sour Water(non-phenolic) Mixture NH3,H2S,H2O 41085 Sour Water(phenolic) Sour Water 28258507 SPC 2300 Mixture 6011 Special Textiles Mixture 2006 Sponge Oil Light Hydrocracked Distillate 3756 C. SRGO Intermediate Gas Oil 68228907 Stabilizer Overhead Mix Iso-Butane,Butane 8906 Steam/Condensate Steam/Condensate 2421 Steaval A Unocal Steaval A 5001 Steaval B Unocal Steaval B 2076 k, Stripper Feed Fuel,Aviation,Turbine Engine 25724 Stripper Overhead Fuel,Aviation,Turbine.Engine 3753 Sulfur Froth Sulfur Froth 1438 Sulfur,Molten Sulfur,Molten 781356 Sulfuric Acid Sulfuric Acid 321679 9 Sullube 32 1430 Super Motor Oil lOw/40 Unocal Super Motor Oil lOw/40 11654 Super TK 208 Gasoline 1356 Tail Gas Mixture N2,112&H2S 1654 Tech T-26 Cleaner Tech T-26 Cleaner 27960 The Natural 2 The Natural 2 7719 Tolad SX 9235 Mixture 16654 Toluene Toluene 1003 Transformer Insulation Oil Mixture 3751 Trichloroethane 1,1,1 Trichloroethane 7307 Triton Gas Engine Oil 30 Crankcase Oil 7364 Turbine Oil 100 Unocal Turbine Oil 100 5358 Turbine Oil 150 Unocal Turbine Oil 150 2492979 Turbine Oil 220 Unocal Turbine Oil 220 2479714 Turbine Oil 32 Unocal Turbine Oil 32 50543 °i Turbine Oil 46 Unocal Turbine Oil 46 6183 Turbine Oil 68 Unocal Turbine Oil 68 2497107 U200 Cracked Naphtha Heavy Thermalcracked Naphtha 395883 U228 Dehexanizer Feed Mix Hydrodesulf Ker, Lt Naphtha 58259 - 8 - Note: Sources for this table arc the Refinery's 1995 Business Plan, 1995 Biennial Report to Cal-EPA,and excluded recyclable material records of transport. Table 1 List of Hazardous Materials and Wastes Stored in Refinery in 1995 -- Baseline Common Name Chemical Name/Composition Haz. Category A Haz. Category B Haz. Category C (pounds) (pounds) (pounds) U228 Reactor Charge Lt Naphtha C4-C10 97524 U228 Reactor Effluent Mix H2&Iso-&N-05,C6 26849 U229 Reactor Charge Sour Mid-Barrel USD 64296 U229 Reactor Effluent Mix H2&Sour Mid-Barrel USD 2145 U230 Reactor Charge Mix H2&Sour C4-C9 1275 U230 Reactor Effluent Mix H2&Hydro Lc.-Heavy Naphtha 1613 I -- U231 Reactor Charge Mix H2&Lt.Reformate Naphtha 1538 U231 Reactor Effluent Mix H2&Lt.Reformate Naphtha 3137 !_ U231 Reactor Effluent With H2 Mix H2&Lt. Reformate Naphtha 5 U240 Cracked Naphtha Light Naphthenic Vacuum Distillate 42094 --.y U240 SC-1 Light Paraffin Vacuum Distillate 32799390 '. U240 SC-2 Heavy Paraffin Vacuum Distillate 46987658 --- U240 SC-2,VTHGO,Seal Oil Heavy Paraffin Vacuum Distillate 136505 U244 Reformate Light Reformate Naphtha 131218 77 U267 Gasoline-Light Naphtha Full Range Straight Run Naphtha 19031 U267 Resid-Vacuum Tower Ban Vacuum Tower Bottoms 66621 U267 Waxy Diesel-Heavy Diesel Light Paraffin Vacuum Distillate 44706 Unix AW 32 Unocal Unix AW 32 580 Unax AW 46 Unocal Unax AW 46 593 8 l Unconverted Oil Heary Hydrocracked Distillate 21386934 i Unicracker Charge Light Paraffin Vacuum Distillate 75329 Union Petrolatum Unocal Petrolatum 105 675686 l Unionfined Naphtha Hydrodesuifurized Heavy Naphtha 3438524 Unoba EP-2 Grease Unocal Unoba EP Grease#2 5656 Unocal 76 Gasoline Gasoline 8627 Unocal Diesel No.2 Mixture(Fuel Oil No.2) 3497 769 Unocal Light Alkylation Naphtha Petroleum Distillates Mixture 2436 Unsmbilized Reformate Light Reformate Naphtha 25642 ! Unstable Magnafotmate Full Range Reformate Naphtha 22051 Unstripped Light Diesel Light Gas Oil 62956 UOP Moleculat Sieve Type 4ADG Catalyst Mixture 10200 Vac Tower Heavy Gas Oil Heavy Paraffin Vacuum Distillate 79883 Vacuum Column Bottom Light Paraffin Vacuum Distillate 134238 Vacuum Tower Bottoms Vacuum Tower Bottoms 18674 Vacuum Tower Feed Petroleum Crude Oil 136746 1 Vacuum Tower Light Gas Oil Light Thermal Cracked Distillate 98451 I r: Waste Water Process Waste Water 172453835 =-+ Waste Water Sludge-MOSC Waste Water Sludge 264799 Wax(off-grade) Solvent Slack Wax 381910 Waxy Diesel Stock Light Paraffinic Vacuum Distillate 20894664 Waxy Naphtha Heavy Naphtha 25661295 -- Waxy Naphtha-Medium Naphtha Heavy Naphtha 32959 Wet Gas Refinery Sour Fuel Gas and H2O 300 Wrico CTC-705 Hexavalent Chromium Compounds 1103 Total Obs.) 1669060 1086073714 1167674634 Total(tons) 835 543037 583837 Note: Sources for this table are the Refinery's 1995 Business Plan. 1995 Biennial Report to Cal-EPA,and excluded recyclable material records of transport. J Transportation Baseline To prepare the transportation baseline, we have at this time chosen to include only those materials transported out of the facility by truck. Truck transportation is the method by which all of the regulated materials are transported for the Selenium _.. Removal Project. Data for materials transported out of the facility are regularly tabulated and easily available. For the sake of this evaluation, we did not include the wi-'e variety of materiz's regularly purchased and transported in since: ' 1. The size of the truck transportation baseline compiled as described is already very large compared to the amounts transported for the Selenium Removal Project, and; 2. Data on purchased materials by transportation method would be very time consuming to assemble and would not change the calculated hazard score for the Selenium Removal Project. 7 Whereas a small amount of Category A material is generated and stored as a result of m, the Selenium Reduction Project, only Category B and C p,°-eject-related matdrials are w transported into SFR and only Category C project-related wastes are transported from SFR. As such, the following transportation summary tables address Category B and C materials and wastes. The amounts of hazardous materials and wastes transported by truck into or from SFR in 1995 are summarized in Tables 2 and 3. As shown, approximately 38,700 tons of Category B materials and 12,800 tons of Category C materials were transported in the 1995 baseline period. J - 10 - I Z - r yl m I l7 4...-�-► o J d w' 1 �_�___ u In 1 UJ � --��►' y zI r U tn 04a N J Q Z V Zr' Q�r v JWo W 0Wj U N way a N �z� a Q z r aI)- x, x Z d C4 �= a w� � iKraaN3�3a aanana 4Z tU/} =00 Q p� cin d z a pr � o zx to W OW.o J Z O Q� FO V aZ aZ w W< Q<?u Yu cS LL. U,N C1 N Y* }w,.Q WMM 2 dQ LLW N Z �+ OG 2 xKWaa WO Q %1wwa ZoQa .. C:fla w 00.4 -.10 R F7jaN= !-aw O� 7' Y NOQwz Qya f • • • • a uva a WZW aam v u r r N a -- a Ln to a 0 Table 2 List of Hazardous Materials and Wastes Transported by Truck to or from Refinery in 1995 -- Baseline ° Common Name Chemical Name/Composition Haz. Category Transport Mode of Tons in In/Out Transport 1995 771 Acetone Acetone B I T Acetylene Acetylene B I T Activated Alumina Activated Alumina C I T Activated Carbon Carbon A I T ADA Elvada-Anthraquinone Disulphonic Acid B I T Adsorbent, H-2 Activated Carbon A I T Ammonia(Anhydrous) Ammonia(Anhydrous) A I T Ammonia Acid Gas Ammonia Acid Gas C I T Ammonia Hydroxide Ammonia Hydroxide C I T Ammonium Polysulfide Mixture B I T Andero1497 Anderol497 C I T Anthracite(Coal) Coal C I T AO-37 AO-36, UC-200 B I T Argon Argon C I T ATF Multipurpose ATF Multipurpose C I T Balanced Polymer 7417 Balanced Polymer 7417 B I T Betz 2023 Mixture B I T Betz 20K Mixture B I T Betz 2OK-20275 Mixture B I T �+ Betz 2OK-20435 Mixture C I T Betz 29K-35144 Mixture B i T Betz 407C Mixture B I T Bar AD-9 Mixture C I T —' Betz Balance Polymer 5430 Mixture B I T Betz Balanced Polymer 64Y21 Mixture B I T Betz Balanced Polymer 7417 Mixture B I T Betz Balanced Polymer AP-111 Mixture B I T Betz Balanced Polymer CF-1 Mixture B I T a Betz Corr-Shield Mixture B I T Betz Corr-Shield 736 Mixture C I T Betz Corr-Shield K-7 Mixture B I T Betz Corrogen Mixture B I T Betz CS-736 Mixture-Betz proprietary B I T Betz CTP 23 Mixture B I T Betz Optimeen 80102 Mixture B I T Betz Optimeen 80103 Mixture B I T Betz Petromeen AF 107 Mixture B I T Betz Petromeen AF-111 Mixture B I T Betz Petromeen FC-644 Mixture B I T Betz Petromeen OS-16 Mixture B I T Betz Slimicide C-31 Mixture B I T ti Betz Slimicide C-77P Mixture C I T Betz Slimicide J-12 Mixture B I T BHT 2,6-di-tert-butyl-4-methylphenol B I T BRAYCO 1350 Brayco 1350 B I T Carbon Dioxide Carbon Dioxide C I T Catacarb 274 Catacarb 274 B I T Catacarb Inhibitor 100-H Catacarb Inhibitor 100-H B I T Catacarb WBU Catacarb WBU B I T Catalyst, E-603 Catalyst Mixture B I T Catalyst, 11-3 Catalyst Mixture B I T Catalyst,23-1, 3, &4 Catalyst Mixture B I T Catalyst, 32-4 Catalyst Mixture B I T Catalyst, 83-2 Catalyst Mixture B I T • — 11 — Note: Sources for this table are the Refinery's 1995 Business Plan, 1995 Biennial Report to Cal-EPA,excluded recyclable material records of transport,and the Accounting Dept.records of transport. Table 2 J List of Hazardous Materials and Wastes Transported by Track to or from Refinery in 1995 -- Baseline Common Name Chemical Name/Composition Haz. Category Transport Mode of Tons in In/Out Transport 1995 Catalyst,AS-100 Catalyst Mixture B I T Catalyst,Claus A-203(Cl) Activated Alumina B I T Catalyst, E-611 Catalyst Mixture B I T Catalyst,E-803 Catalyst Mixture B I T Catalyst, E-804 Catalyst Mixture B I T Catalyst,HC-26/28,HCK Catalyst Mixture B I T Catalyst,HCD, HCK Catalyst Mixture B I T Catalyst,HCK Catalyst Mixture B I T i Catalyst,HCKIAF-542 Catalyst Mixture B I T Catalyst,HS-10 and denstone Catalyst Mixture B I T Catalyst,HS-10,denstone Catalyst Mixture B I T Catalyst,Katalco 41-6 Catalyst Mixture B I T Catalyst,Katalco 71-1 Catalyst Mixture B I T Catalyst,KF-844 Catalyst Mixture B I T Catalyst,N-25, N-39 Catalyst Mixture B I T Catalyst,S-501 Catalyst Mixture B I T ,I Catalyst,TSR-11 Catalyst Mixture B I T Chlorine Chlorine A I T Citm Super Parts Degreaser D-Limonene C I T Diala AX OR Diala Oil AX B I T Diatomaceous Earth Diatomaceous Earth C I T Dye,Automate Red B Dye,Automate Red B B I T Epolene-C-18 Mixture C I T Ethanol Ethanol B I T Excluded Recylable Material Wastes used off-site as Raw Material Feed A 0 T Freon II Trichlorofluoromethane C I T Fyrquel 550 R and 0 Fyrquel 550 R and 0 B I T Gas Mixture:CO/N2 Mixture C I T Gas Mixture:CO2/Argon 75%Argon 25% CO2 C I T Gas Mixture:CO2/N2 Mixture C I T l Gas Mixture:H2/Ethane/Methane Mixture B I T Gas Mixture:H2S/N2 Mixture C I T Gas Mixture: Helium/Methane Mixture B I T Gas Mixture:Methane/Ethane Mixture B I T Gas Mixture: N2/Methane Mixture B I T Gas Mixture: NOx/N2 Mixture C T Gas Mixture:02/N2 Mixture C I T Gas Mixture: Pentane/Butane 3% iso-Butane 3% n-Pentane 94% n-Butane B I T Gas Mixture: Propane/Butane 3%n-Butane 3%a Propane 9435 iso-Butane B I T Gas Mixture: S02/Air Mixture C I T Glycol Diethylene Glycol B I T GW Solv 225 Mixture B I T GW Solv 325 Standard Solvent B I T Hazardous Waste Waste--Hazard Category A A 0 T Helium Helium C I T Heptane N-Heptane B I T Hydrogen Hydrogen B I T Isopropyl Alcohol Isopropyl Alcohol B I T ISOSIV Molecular Sieve Adsorbent Catalyst Mixture B I T Lapping Vehicle N 3 Lapping Vehicle N 3 C I T MORON SA MEA Monoethanolamine C I T — 12 — Note: Sources for this table are the Refinery's 1995 Business Plan, 1995 Biennial Report to Cal-EPA,excluded recyclable materia:records of transport,and the Accounting Dept. records of transport. • • Table 2 List of Hazardous Materials and Wastes Transported by Truck to or from Refinery in 1995 -- baseline Common Name Chemical Name/Composition Haz. Category Transport Mode of Tons in In/Out Transport 1995 Methel Ethol Ketone 2-Butanone B I T Y MIBK Methyl Iso-butyl ketone B I T Mineral Oil,Heavy Mineral Oil C I T Mineral,Light (Blandol) Mineral Oil C I T Mix Dewaxed Long Raffinate&Propane Mix Sol. Dewaxed Lt.Paraffinic Dist&Propane C I T Mobiltherm 603 Mobiltherm 603 B I T Motor Oil (Guardol 30) Oil,Petroleum n.o.s. C I T 7 Motor Oil lOw/40 Unocal Super Motor Oil lOw/40 C I T MP Gearlube 80w/90 Unocal MP Gearlube 80w/90 C I T a Nalco 1193 Mixture B I T Nalco 39M Mixture C I T Nalco 5165 Mixture B I T 'e Nalco 5196 Mixture B I T Nalco 5196&Petrolite 1150 Nalco 5196&Petrolite 1150 B I T Nalco 5537 Mixture B I T Nalco 5651 Mixture B I T Nalco 5707 Mixture C I T Nalco 7330 Mixture B I T Nalco 7346 Mixture C I T Nalco 8305 Mixture B I T -- Nalco Ultrion 7156 Mixture B I T Nitrogen Nitrogen C I T - • Nitrous Oxide Nitrous Oxide C I T Octane(88-Octane Reference Fuel) Mixture B I T Octane(Iso-octane) 2,2,4-Trimethylpentane B I T Octane Blend(80 Octane Blend) Mixture B I T Oxygen Oxygen C I T a Pet 1330 Mixture C I T Petrolite 1150 Mixture B I T Phenol Phenol A I T Phosphoric Acid Phosphoric Acid C I T Potassium Hydroxide 50% Solution Potassium Hydroxide B I T Prime Cleaner Mixture B I T Propane Propane B I T PSA H-2 Adsorbent Activated Carbon A I T PSA H-3 Adsorbent Silica Gel C I T PSA H-5 Adsorbent Activated Alumina C I T Silicia Gel K3 Silica Gel A I T Silicone Antifoam Agent SW-03461 Mixture C I T Silicone SWS-03461 Silicone SWS-03461 B I T Soda Ash Sodium Carbonate,Anhydrous C I T Sodium Ammonium Vanadate Vanadium Compounds(Elvan K) A I T Sodium Hydroxide Sodium Hydroxide B I T Sodium Hydroxide 50% Solution Sodium Hydroxide B I T Solvent GW 450 Solvent GW 450 C I T SPC 2300 Mixture B I T Special Textiles Mixture B I T Steaval A Unocal Steaval A C I T Steaval A Unocal Steaval A C I T `-' Steaval B Unocal Steaval B C I T _ >• .� ..rte.-,..�__ �. �-�-�.� �.�.:,� y �- Sulfuric Acid Sulfuric Acid B I T Sullube 32 Sullube 32 B I T Tech T-26 Cleaner Tech T-26 Cleaner B I T 13 — Note: Sources for this table are the Refinery's 1995 Business Plan. 1995 Biennial Report to Cal-EPA,excluded recyclable material records of transport,and the Accounting Dept. records of transport. Table 2 List of Hazardous Materials and Wastes Transported by Truck to or from Refinery in 1995 -- Baseline ' Common Name Chemical Name/Composition Haz. Category Transport Mode of Tons in WOut Transport 1995 The Natural 2 The Natural 2 C I T Tolad SX 9235 Mixture B I T Toluene Toluene B I T Transformer Insulation Oil Mixture B I T Trichloroethane 1,1,1 Trichloroethane A I T J Triton Gas Engine Oil 30 Crankcase Oil B I T TSX Motor Oil 30 TSX Motor Oil 30 B I T Turbine Oil 100 Unocal Turbine Oil 100 C I T Turbine Oil 150 Unocal Turbine Oil 150 B I T Turbine Oil 220 Unocal Turbine Oil 220 C I T Turbine Oil 32 Uriucal Turbine Oil 32 C I T Turbine Oil 46 Unocal Turbine Oil 46 C I T 3 Turbine Oil 460 Unocal Turbine Oil 460 C I T w Turbine Oil 68 Unocal Turbine Oii 68 B I T Unax AW 32 Unocal Unax AW 32 C I T Unax AW 46 Unocal Unax AW 46 C I T Unoba EP-2 Grease Unocal Unoba EP Grease#2 B I T UOP Moleculat Sieve Type 4ADG Catalyst Mixture B I T i Wrico CTC-705 Hexavalent Chromium Compounds B 1 T Total Hazard Category C Material and Waste Transported by Truck from Refinery in 1995—51541 Tons r :a J - 14 - Note: Sources for this table are the Refinery's 1995 Business Plan, 1995 Biennial Report to Cal-EPA,excluded recyclable mata:ial records of transport,and the Accounting Dept.records of transport. Table 3 Summary of Hazardous Materials and Wastes Transported by Truck from Refinery in 1995 " -- Hazard Categories B &C -- 1 ,.a Hazard Category B: Material or Waste T4I1S Slack Wax 599 Sulfur, molten 30776 Union Petrolatum 7215 Hazardous Waste 98 Total 38688 a Hazard Category C: Material or Waste Tons Aristowax 10646 Foots Oil 1419 Lube Oil 620 Hazardous Waste 168 Total 12853 1 74 rJ Note: Sources for this table are the Refinery's 1995 Business Plan, 1995 Biennial Report to Cal-EPA. and the Accounting Dept. records of transport. "3 �- — 15 — 5.0 Project Determination The following project determination describes a range of project risk scores for the Selenium Reduction Project pursuant to the Contra Costa County Land Use Ordinance i #96-20, Article 84-63.10. Selenium Removal Project Storage Amounts Project storage amounts have been calculated based upon the entire estimated storage volume including storage tanks, process equipment, and piping. It should be noted that detailed design of the project has not been completed, and as a result, final constructed 1 volumes may change slightly. Project materials and wastes have been tabulated to include purchased reagents and metals-containing materials and wastes. As shown in Table 4, purchased reagents- are listed according to their DOT classification found in 40 CFR Section 172.101. However, the assignment of DOT classifications in Table 4 to the regenerant solutions and project wastes has resulted from thorough review and evaluation by an in-house wl toxicologist and substantiated by independent experts. Refer to Appendix A for toxicological report. All project metal-containing solutions and solid waste streams have been classified to a hazard category pursuant to Contra Costa County Land Use #96-20, Article 84- 63.1016. All but one have been assigned Category C. An intermediate waste stream (Stream #26 in toxicological report) was assigned to Category A, because of its potential to be classified as a DOT poison. Total storage of Category A material is 0.12 tons. -.1 Category B materials are the following purchased reagents used in the process: sodium hydroxide solution and sodium sulfide solution. Total storage of these Category B materials is 47 tons. .:i Category C materials are the following purchased reagent, regenerant solutions, and wastes: Copper Chloride, the sludge from the regenerant recovery, and the recycled �T? regenerant. The recycled regenerant is listed in total, since the toxicology evaluation -- showed that the LD50 was greater than the constituent concentrations at all points in the process. Total amount of Category C material stored is approximately 600 tons. Other materials used in the process are not DOT regulated and as such have not been assigned to a hazard category. - 16 - A Selenium R moval Process Transportation Amounts -� The development of transportation amounts for the Selenium Removal Project was based upon the nominal output from SFR's sour water strippers that feed the Selenium Reduction Project. T- ble 5 summarizes Droject materi�.ls and wastes by hazard category that will be transported either into or out of SFR as a result of the project. As shown, 198 tons per "' year of Category B materials and wastes, and 203 tons per year of Category C materials and wastes are anticipated. When compared to the transportation baseline previously discussed, the changes in transportation are 0.51 and 1.59 per cent, respectively for Categories B and C. Since there is no Category A materials or wastes ' transported either into or out of SFR as a result of this project, the percent change is zero. - 18 - 77 Table 5 Transportation Analysis Project Transportation Estimate (assumes nominal flow of 220 gpm) Category A Materials -- none transported in or out of refinery Category B Materials -- Daily Transportation Tons Sodium Hydroxide 10 gallons 0.04 tons/day Sodium Sulfide 119 gallons 0.51 tons/day Total Category B Transportation 0.54 tons/day Total in Tons/Year 198.29 u� Category C Materials -- Daily Transportation Copper Chloride 59 gallons 0.30 tons/day Sludge Production 0.26 tons/day Total Category C Transportation 0.56 tons/day Total in Tons/Year 203 Transportation Baseline �v total Category A materials N/A total Category B materias 38688 tons/year total Category C materials 12753 tons/year Change In Transportation per cent change in Category A N/A per cent change in Category B 0.51 per cent -' per cent change in Category C 1.59 per cent 19 - i 6.0 Assessment of Risk Elements This section discusses the assignment of individual risk elements for calculation of the project hazard score, referring to the appropriate tables in Contra Costa County Ordinance No. 96-20. • Community Risk Element _ For the sake of completeness, project hazard scores evaluating two community risk elements will be evaluated. The closest receptor is an area of land designated as residential located approximately 900 feet from the nearest boundary of the Selenium Removal Project. Referring to Article 84-63.1004 of the ordinance, under the table for Community Risk. (C) and section labeled "Type of Receptor", the hazard element for residential property is 5. The Tiny Tot Day Care and Nursery School in Bayo Vista is located approximately 1600 feet from the nearest boundary of the Selenium Reduction Project. The Community Risk hazard element for that location is 7. • Per Cent Cha=ige in Storage For Category A materials and wastes, the per cent increase in storage is expressed as: (0.12/835)x100 which equals 0.014 per cent. Referring to the table in the ordinance labeled Pa Cent Change (P), the hazard score for this element is between 0 and 1%, yielding a score of zero. _.y For Category B materials and wastes, the per cent increase in storage is expressed as: (47/543,000)x 100 which equals 0.0087 per cent. Referring to the table in the ordinance labeled Pfr Cent Change (P), the hazard score for this element is between 0 and 1%, yielding a score of zero. For category C materials and wastes, the per cent increase in storage is expressed ` as: (600/583,000)x100 which equals 0.103 per cent. This change is also less than I%, giving a score of zero. - 20 - i J • Hazard Categories q As discussed above, the Selenium Removal Project involves Category A, Category B, and Category C materials and wastes. From the table labeled Hazard Category of Material (H) in the ordinance, the scores for these categories are 5, 3 and 1 respectively. • Distance -� The nearest distances to receptors, as previously discussed, are 900 feet to the residentially zoned property and 1600 feet to the nearest sensitive receptor. From the table in the ordinance labeled Community Risk. Distance to Receptor (D), the scores for these distances are 25 and 23, respectively. • Amounts of Material or Waste Stored The amounts of material and wastes stored are 0.12 tons, 47 tons, and 600 tons, respectively for Categories A, B, and C materials. From the table in the ordinance labeled FACILITY RISK: SIZE OF PROJECT. Total Amount of ghange. tons wJ the scores for these amounts are 2, 16 and 21, respectively. • Project Hazard Score Calculations Using the data and supporting calculations described above, project hazard scores have been developed as shown in Table 6. Six cases have been analyzed to cover the situations that will yield the highest project risk scores. With respect to the residential receptor, Examples 1, 3, and 5 show that the project hazard score for Category A materials is 53, Category B materials is 57, and Category C materials is 52. -- Examining the potential concern for sensitive receptors which are further away, the project hazard scores for Category A, Category B, and Category C materials are 61, 61, and 52, respectively. - 21 - u Table 6 Contra Costa County Land Use Ordinance 96-20 Facilities that Handle Hazardous Materials and Hazardous Wastes :3 Ordinance Formula Score = ((T+C+%) x H) + D + A Example 1 Based on A materials stored & used, residential receptor T is Truck, change <5% Score = 0 C is Residential Score = 5 % is<1 Score = 0 H is Category A Score = 5 D is >700-900 ft Score = 26 A is 0.12 tons Score = 2 Haz. Score is 53 Example 2 Based on A materials stored & used, sensitive receptor T is Truck, change < 5% Score = 0 C is Sensitive Score = 7 % is<1 Score = 0 H is Category A Score = 5 D is >1500-1800 ft Score = 24 A is 0.12 tons Score = 2 Haz. Score is 61 Example 3 Based on B materials stored & used, residential receptor T is Truck, change < 5% Score = 0 C is Residential Score = 5 % is<1 Score = 0 H is Category B Score = 3 D is >700-900 ft Score = 26 -- A is 47.31 tons Score = 16 Haz. Score is 60 `- - 22 - Table 6 Contra Costa County Land Use Ordinance 96-20 Facilities that Handle Hazardous Materials and Hazardous Wastes Example 4 Based on B materials stored & used, sensitive receptor *`1 T is Truck, change < 5% Score = 0 jj C is Sensitive Score = 7 is<1 Score = 0 :9 H is Category B Score = 3 n D is >1500-1800 ft Score = 24 -71 A is 47.31 tons Score = 16 Haz. Score is 61 Example 5 Based on C materials stored & used, residential receptor T is Truck, change < 5% Score = 0 C is Residential Score = 5 % is < 1% Score = 0 H is Category C Score = 1 D is >700-900 ft Score = 26 A is 600 tons Score = 21 Haz. Score is 52 Example 6 Based on C materials stored & used, sensitive receptor T is Truck, change < 5% Score = 0 C is Sensitive Score = 7 % is < 1% Score = 0 H is Category C Score = 1 D is > 1500-1800 ft Score = 24 A is 600 tons Score = 21 Haz. Score is 52 23 ' t 7.0 Non-Coverage As shown above for all six cases analyzed, no score exceeds 69. Furthermore, the Selenium Reduction Project does not increase the total hazardous materials and wastes as compared to baseline for the past three years. The approximate 650 ton increase in managed materials and wastes that results from the Selenium Reduction Project is easily off-set by SFR's approximate 5000 ton reduction in spent stretford solution over the past three years. 8.0 Exemption `4 See Appendix B. 9.0 Conclusions • All project hazard score calculations yielded scores of 61 or below. • The Selenium Reduction Project will not cause an increase in the handling of 7'J hazardous materials or hazardous wastes as compared to SFR's three-year baseline. • No land use permit, or application for exemption, or determination for non- coverage required (Contra Costa County Land Use Ordinance 96-20, Article 84- 63.802. - 24 - ti t � • BYLAWS OF THE CONTRA COSTA COUNTY HAZARDOUS MATERIALS COMMISSION -� I . RESPONSIBILITIES A. Pursuant to Health and Safety Code section 25135 .2, the Contra Costa County Hazardous Materials Commission ( "Commission" ) shall : 1. Advise the County Board of Supervisors, County '? staff, and the mayors, council members, and staffs of the cities within the county, on issues related to the development, approval, and administration of the county hazardous waste management plan. 2 . Hold informal public meetings and workshops to provide the public with information, and to receive comments, during the preparation of the county hazardous waste management plan. B. Pursuant to Board of Supervisors Order dated October 14, 1986, the Commission is charged with the following tasks: 1. Draft a County Hazardous Materials Storage and Transportation Plan for consideration by the Board of Supervisors. 2. Draft a County Hazardous Materials Storage and .�. Transportation Management Ordinance for consideration by the Board of Supervisors. 3. Coordinate the implementation of the Hazardous Materials Release Response Plan and Inventory program (AB 2185) (Stats. 1985, ch. 1184) with the other recommendations of the Hazardous Waste Task Force and the Hazardous Waste Management -- Plan. (Revised by Commission, April 22 , 1992 ) 4 . Address the economic effects of implementing these recommendations. 5. Further develop the recommendations involving hazardous materials issues which should include obtaining broad public input. 6. Oversee management coordination of all aspects of the storage or transportation of hazardous materials and the generation, storage, transportation, treatment, and disposal of hazardous waste. 7 . Recommend further charges for consideration by the Board of Supervisors, or recommend changes in the existing charges to the Commission for consideration by the Board of Supervisors. :<T 1 Hazardous Materials Commission Bylaws C. Report and make recommendations on such further matters concerning hazardous materials and wastes as are referred to the Commission by the Board of Supervisors. II. MEMBERSHIP A. Members . The Commission shall consist of the following twelve ( 12) members, appointed as follows: One member of the Board of Supervisors, appointed by the Board of Supervisors; Two representatives of cities, appointed by the City Selection Committee pursuant to Article 11 (S 50270 et seq. ) of Chapter 1 of Part 1 of Division I of Title 5 of the Government Code. �. Two representatives of business, nominated. by industrial associations, screened by the Internal Operations Committee, and appointed by the Board of Supervisors; Two representatives of environmental organizations, nominated by those organizations, screened by the Internal Operations Committee, and appointed by the Board of Supervisors; One representative of taxpayers, recommended by the Internal Operations Committee and appointed by the Board of Supervisors; One representative of the League of Women Voters, nominated by the League and appointed by the Board of Supervisors; One labor representative, nominated by labor -� organizations, screened by the Internal Operations Committee, and appointed by the Board of Supervisors; One representative of environmental engineering firms located in Contra Costa County, nominated by such firms, screened by the Internal Operations Committee, and appointed by the Board of Supervisors ; One representative of the general public, appointed by the Board of Supervisors . (Health & Saf. Code, § 25135.2; Bd. Order dated 10-14-86 . Amended 2-14-94 . ) B. Board Appointments. Board of Supervisors ' Resolution No. 77/273 shall govern the procedure for nominating and appointing members appointed by the Board of Supervisors. 2 Y Hazardous Materials Commission Bylaws 5 C. Terms . Members shall serve staggered terms of four- years at the pleasure of the appointing authority. There is no limit to the number of terms a member may serve. The Commission shall determine how the terms shall be staggered. D. Alternates. Organizations nominating or appointing members to serve on the Commission may designate alternates to members of the Commission by submitting the name of the alternate to the County Administrator. If the Board of Supervisors is the appointing authority, the County Administrator shall seek Board approval of the appointment, which becomes effective upon Board approval . (Bd. Order dated 8-18-87 . ) III. OFFICERS A. The Commission shall elect a Chairperson and a Vice- chairperson for terms of one calendar year. B. The Clerk of the Board shall be notified of the - selection of the Chairperson and Vice-chairperson. C. The Chairperson and Vice-chairperson may serve -= consecutive terms. IV. CONDUCT OF BUSINESS .W A. Meetings. Meetings shall be conducted pursuant to the Ralph M. Brown Act. (Gov. Code, S 54950 et seq. ) B. Chairperson. The chairperson shall be responsible for: 1. Conducting all meetings of the Commission. 2. Reviewing and approving Commission agendas. .i 3. Selecting Commission members for standing and ad hoc committees . 4 . Representing the Commission, or designating a member to represent the Commission, before the Board of Supervisors, City Councils, or other bodies before which the Commission may wish to appear. C. Quorum. Business shall be conducted by the Commission only when a quorum is present. A majority shall constitute a quorum. During periods when one or more seats on the Hazardous Materials Commission is vacant, the vacant positions shall not be -. considered for determining whether a quorum is present. A seat is vacant when there is no commissioner or alternate appointed to serve in that capacity. 3 Hazardous Materials Commission Bylaws D. Final recommendations of the Commission to the Board of a Supervisors shall require eight (8) affirmative votes . V. BYLAWS AND OTHER GUIDELINES A. Bylaws. These Bylaws shall govern the conduct and activities of the Commission. However, nothing in these bylaws ^� excuses compliance with any other law. The Commission may, from time to time, recommend to the Board of Supervisors that changes be made to these bylaws. ° B. Other Guidelines. The Commission may establish other =' guidelines for the efficient conduct of its business not inconsistent with these bylaws. VI. CONFLICT OF INTEREST A. General Board Policy. Pursuant to Resolution No. 82/574, the Board of Supervisors has adopted a policy for Board appointees concerning conflicts of interest. Resolution No. - 82/574 applies to the Commission and requires as follows: - 1. Statutes on Conflicts. Officials, Commissioners, and Committee members appointed by the Board shall adhere to the principles and rules of the Political Reform Act of 1974 (Gov. Code, S 816000 et seq. ) , including the following: (a) Local government should serve the needs and respond to the wishes of all citizens equally, without regard to their wealth. (Gov. Code, S 81001[b] . ) a (b) Public officials should perform their duties in an impartial manner, free from bias caused by financial interests of themselves or their supporters. (Gov. Code, S 81002[b] . ) (c) Public officials should disclose assets and income which may be materially affected by their official actions, and in appropriate circumstances they should be disqualified from acting, in order to avoid conflicts of interest. (Gov. Code, S 81002[d] . ) 2 . Common Law Policy on Conflicts . All officials should so conduct the public business as to avoid even any appearance of conflict of interest. (See, e.g. , Kimura v. Roberts [1979 ] 89 Cal.App.3d 871. ) B. Board Policy for Hazardous Materials Commission. Consistent with Resolution No. 82/574 and Health and Safety Code 4 Hazardous Materials Commission Bylaws I section 25135.2, the Board hereby declares, as a matter of legislative determination, that members of the Hazardous Materials Commission are intended to represent and further the interest of specified industries and groups responsible for their nomination. Accordingly, the Board of Supervisors hereby finds J that for purposes of members of the Commission nominated by a trade, industrial or professional group, such trade, industrial or professional group constitutes a significant segment of the public within the meaning of Government Code section 87103. By this policy, the Board does not find or imply tha_- members of the Hazardous Materials Commission are public officials within the meaning of Government Code section 87100 (Political Reform Act) . This declaration of policy is only to clarify the application of the Board's general policy on conflict of interest to the Hazardous Materials Commission. (Approved by the Board of Supervisors on October 16, 1989. Non-substantive amendments by the commission on April 22, 1992. Amended by the Board of Supervisors on February 14, 1994. ) w:. LTF lOhmc21494. °I 1 5